最終更新日：2022/12/24
In the complexes, the direction and affinity of the hydroxy group for hydrogen bond toward the carboxy group of poly-12 may be the most important factor to control both the helical sense and an extent of the single-handedness, and therefore, the complexes with amino alcohols showed an intense ICD independent of the bulkiness of the substituent (R) with the same Cotton effect signs as the primary amines.
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元となった例文
In
the
complexes,
the
direction
and
affinity
of
the
hydroxy
group
for
hydrogen
bond
toward
the
carboxy
group
of
poly-12
may
be
the
most
important
factor
to
control
both
the
helical
sense
and
an
extent
of
the
single-handedness,
and
therefore,
the
complexes
with
amino
alcohols
showed
an
intense
ICD
independent
of
the
bulkiness
of
the
substituent
(R)
with
the
same
Cotton
effect
signs
as
the
primary
amines.
