corset effect
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(chemistry) With regard to a stable tetrahedrane derivative with four tertiary butyl substituents enveloping the tetrahedrane core, the theory that bonds in the core are prevented from breaking because this would force the substituents closer together, resulting in van der Waals strain.
corset effect
The stability of a tetrahedrane derivative with four tertiary butyl substituents enveloping the core is explained by a corset effect: bond breaking would force the substituents closer together, producing prohibitive van der Waals strain.
The stability of a tetrahedrane derivative with four tertiary butyl substituents enveloping the core is explained by a corset effect: bond breaking would force the substituents closer together, producing prohibitive van der Waals strain.
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