Last Updated：2025/12/05
The stability of a tetrahedrane derivative with four tertiary butyl substituents enveloping the core is explained by a corset effect: bond breaking would force the substituents closer together, producing prohibitive van der Waals strain.
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The stability of a tetrahedrane derivative with four tertiary butyl substituents enveloping the core is explained by a corset effect: bond breaking would force the substituents closer together, producing prohibitive van der Waals strain.
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コアを取り囲む4つの第三級ブチル置換基を持つテトラヘドラン誘導体の安定性は、立体的拘束によって説明される。結合が切れると置換基同士が近づかざるを得ず、許容できないほどのファンデルワールスひずみが生じるからだ。
