Kulinkovich reaction
( plural )
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(organic chemistry) The organic synthesis of cyclopropanols via reaction of esters with dialkyldialkoxytitanium reagents, generated in situ from Grignard reagents bearing hydrogen in beta-position and titanium(IV) alkoxides such as titanium isopropoxide.
Kulinkovich reaction
The Kulinkovich reaction converts esters into cyclopropanols by employing dialkyldialkoxytitanium species generated in situ from Grignard reagents that possess a beta-hydrogen together with titanium(IV) alkoxides such as titanium isopropoxide.
The Kulinkovich reaction converts esters into cyclopropanols by employing dialkyldialkoxytitanium species generated in situ from Grignard reagents that possess a beta-hydrogen together with titanium(IV) alkoxides such as titanium isopropoxide.
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