Last Updated：2025/11/26
Sentence
エステルを、β位に水素を有するグリニャール試薬とチタン(IV)アルコキシド（例えばイソプロポキシチタン）からその場で生成されるジアルキルジアルコキシチタン試薬を用いてシクロプロパノールに変換する有機合成法は、エステルをシクロプロパノールへと変換する。
Quizzes for review
The Kulinkovich reaction converts esters into cyclopropanols by employing dialkyldialkoxytitanium species generated in situ from Grignard reagents that possess a beta-hydrogen together with titanium(IV) alkoxides such as titanium isopropoxide.
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The Kulinkovich reaction converts esters into cyclopropanols by employing dialkyldialkoxytitanium species generated in situ from Grignard reagents that possess a beta-hydrogen together with titanium(IV) alkoxides such as titanium isopropoxide.
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Related words
Kulinkovich reaction
Noun
Japanese Meaning
有機合成法の一種。エステルとβ-水素を有するグリニャール試薬およびチタン(IV)アルコキシド（例えばチタンイソプロポキシド）から原位で生成される二アルキル二アルコキシチタン試薬を反応させ、シクロプロパノールを合成する反応
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