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：2025/11/26
semipinacol rearrangement
（ plural ）
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(organic chemistry) A rearrangement involving a carbocation with a hydroxy group adjacent to the electron-deficient centre.
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semipinacol rearrangement
The semipinacol rearrangement provided a straightforward route to the ketone by migrating the adjacent substituent after carbocation formation.
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The semipinacol rearrangement provided a straightforward route to the ketone by migrating the adjacent substituent after carbocation formation.
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