Last Updated:2025/12/30
Sentence
The
formation
of
azeotropes
due
to
deviations
from
Raoult's
law
was
discussed
in
Section
1.3.
An
azeotrope
is
a
mixture
that,
at
a
given
pressure
(the
azeotropic
pressure),
boils
at
a
constant
temperature
(the
azeotropic
temperature),
and
has
the
same
composition
(the
azeotropic
composition)
in
the
equilibrium
vapor
and
liquid
phases.
Homogeneous
azeotropes
are
those
that
form
one
liquid
phase
at
equilibrium
with
the
vapor;
heterogeneous
azeotropes
are
those
that
form
two
liquid
phases
at
equilibrium
with
each
other
and
the
vapor.
Quizzes for review
The formation of azeotropes due to deviations from Raoult's law was discussed in Section 1.3. An azeotrope is a mixture that, at a given pressure (the azeotropic pressure), boils at a constant temperature (the azeotropic temperature), and has the same composition (the azeotropic composition) in the equilibrium vapor and liquid phases. Homogeneous azeotropes are those that form one liquid phase at equilibrium with the vapor; heterogeneous azeotropes are those that form two liquid phases at equilibrium with each other and the vapor.
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