Last Updated:2025/11/21

At constant temperature and volume, the equilibrium composition of the reaction is found by minimizing the system's free energy A = U − TS.

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At constant temperature and volume, the equilibrium composition of the reaction is found by minimizing the system's free energy A = U − TS.

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温度と体積が一定の場合、反応の平衡組成は系のヘルムホルツ自由エネルギーA=U−TS(内部エネルギーからエントロピーと絶対温度の積を引いたもの)を最小化することで求められる。

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